Just figured out that it is possible to blog directly from word via the xmlrpc.php script!
To enable it, you have to allow it in WordPress itself
Settings -> Writing -> Remote Publishing
If you don’t do this, Word will give you a “Word Cannot Register Your Account” error.
Thanks http://thebalancequest.com/blogging/wordpress-settings-%E2%80%9Cword-cannot-register-your-account%E2%80%9D-error for the tip! I did not sit all night thanks to you 😛
In word, just press new and “blog post”, and word will help you set it up.
Now for the result… Edit: Success!